Chemical Tests

GCSE Chemistry cheat sheet · Chemical analysisThis is a free GCSE Chemistry cheat sheet on chemical tests, covering the key ideas in chemical analysis on a single page. Read it below, download it as a PNG or PDF, or print it out for your wall.

cheat sheet

The Chemical Tests cheat sheet: a one-page GCSE Chemistry summary of chemical analysis.

Chemical Tests - GCSE Chemistry cheat sheet

Chemical Tests

Gas tests, flame tests, cation tests with NaOH, and anion tests for halides, sulfates, nitrates and carbonates.

Illustrated by Cognito Art Team · Reviewed by Emily

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Gas tests

Each common gas has a specific test with a characteristic positive result.

GasTestPositive result
H₂ (hydrogen)Bring a lit splint to the gasLit splint gives a squeaky pop
O₂ (oxygen)Insert a glowing splintGlowing splint relights
CO₂ (carbon dioxide)Bubble the gas through limewaterLimewater turns milky
Cl₂ (chlorine)Expose damp blue litmus paperLitmus paper bleached white
NH₃ (ammonia)Expose damp red litmus paperLitmus paper turns blue
H₂O (water vapour)Add the gas to anhydrous copper sulfateAnhydrous copper sulfate turns white to blue

Flame tests

Method: Clean a nichrome wire loop, dip in dilute HCl, dip in sample, then place in a Bunsen flame.

CationLi⁺Na⁺K⁺Ca²⁺Cu²⁺Ba²⁺
Flame colourCrimsonYellowLilacOrange-redGreenApple green

Colours can be weak or masked by other ions. Clean the wire loop thoroughly between tests.

Cation tests with NaOH (aq)

Method: Add a few drops of NaOH(aq) to the solution.

CationObservation (precipitate colour)In excess NaOH
Al³⁺White precipitateDissolves
Ca²⁺White precipitateInsoluble
Mg²⁺White precipitateInsoluble
Cu²⁺Blue precipitateInsoluble
Fe³⁺Brown precipitateInsoluble
Fe²⁺Green precipitateInsoluble
Zn²⁺White precipitateDissolves

Al³⁺ and Zn²⁺ both give a white precipitate that dissolves in excess NaOH - they form soluble hydroxide complexes.

Anion tests

Halide tests

Method: Acidify with dilute HNO₃, then add AgNO₃(aq).

  • Cl⁻ (chloride) - white precipitate forms; soluble in dilute NH₃
  • Br⁻ (bromide) - cream precipitate forms; soluble in concentrated NH₃
  • I⁻ (iodide) - yellow precipitate forms; insoluble in NH₃

Sulfate test

Method: Acidify with dilute HCl, then add BaCl₂(aq).

  • SO₄²⁻ (sulfate) - white precipitate forms.

Nitrate test

Method: Add NaOH(aq) and aluminium powder, then warm gently.

  • NO₃⁻ (nitrate) - ammonia gas is given off; pungent smell of ammonia; damp red litmus paper turns blue.

Carbonate test

Method: Add dilute acid (e.g. HCl).

  • CO₃²⁻ (carbonate) - carbon dioxide gas given off; effervescence (bubbling); limewater turns milky.
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