5.4 - Nuclear Decay Equations
Balancing a nuclear equation
- A nuclear equation shows radioactive decay using nuclide symbols.
- It's written with the nucleus before decay on the left, an arrow, then the nucleus after decay plus the radiation emitted:
nucleus before decay → nucleus after decay + radiation emitted
Every equation must balance
- Charge and mass are conserved, so the totals can't change across the arrow.
- The total mass number (top numbers) on the left equals the total mass number on the right.
- The total atomic number (bottom numbers) on the left equals the total atomic number on the right.
Alpha decay
- In alpha decay the nucleus emits an alpha particle - two protons and two neutrons (a helium nucleus).
- Because two protons and two neutrons leave the nucleus:
- The mass number decreases by 4
- The atomic number decreases by 2
- Losing two protons changes the nucleus into a different element.
- In a nuclear equation the alpha particle is written as a helium nucleus:
Worked example - Balancing an alpha decay
Uranium-238 decays by alpha emission to thorium. Write the balanced equation.
Step 1 - Apply the alpha decay changes
The alpha particle is , so the mass number falls by 4 and the atomic number falls by 2:
Step 2 - Check the totals balance
- Mass numbers: 238 = 234 + 4
- Atomic numbers: 92 = 90 + 2
Both totals match across the arrow, so the equation is balanced.
Beta decay and gamma emission
Beta decay
- A neutron in the nucleus changes into a proton and emits a fast-moving electron - the beta particle.
- The nucleus loses a neutron and gains a proton, so:
- The mass number stays the same
- The atomic number increases by 1
- The extra proton means a different element is formed.
- A beta particle is written as in a nuclear equation.
Gamma emission
- A nucleus with excess energy releases it as a gamma ray.
- This removes energy only, so the mass number and the atomic number both stay the same and the element does not change.
Worked example - Balancing a beta decay
Carbon-14 decays by beta emission to nitrogen. Write the balanced equation.
Step 1 - Apply the beta decay changes
The beta particle is . The mass number is unchanged and the atomic number rises by 1:
Step 2 - Check the totals balance
- Mass numbers: 14 = 14 + 0
- Atomic numbers: 6 = 7 + (−1)
Both totals match across the arrow, so the equation is balanced.
Neutron emission
- In neutron emission the nucleus gives out a single neutron.
- A neutron has a mass number of 1 and no charge, so:
- The mass number decreases by 1
- The atomic number stays the same
- Because the atomic number is unchanged, the element is the same but becomes a lighter isotope.
Example - Helium-5
Helium-5 emits a neutron to become helium-4:
The mass numbers (5 = 4 + 1) and the atomic numbers (2 = 2 + 0) both balance.
TermDefinition
Alpha particleA particle made of two protons and two neutrons that is emitted from a nucleus during alpha decay.
Beta particleA fast-moving electron emitted from a nucleus when a neutron changes into a proton.
Gamma rayVery high-frequency electromagnetic radiation, usually given out by an unstable nucleus as it loses energy. Giving it out does not change the number of protons or neutrons.
Key points to remember
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