4.2 - Developing the Model of the Atom
The plum pudding model
- In 1897, J. J. Thomson discovered the electron - a tiny, negatively charged particle.
- This showed atoms are not indivisible spheres, but contain smaller charged parts.
- Thomson proposed the plum pudding model:
- The atom is a ball of positive charge.
- Tiny negative electrons are embedded inside it.

Rutherford's alpha scattering and the nuclear model
- In 1909, Ernest Rutherford (with Hans Geiger and Ernest Marsden) fired positively charged alpha particles at a thin sheet of gold foil.
- If the plum pudding model had been correct, the alpha particles should have passed straight through or been deflected only slightly.
Observations and conclusions
- Most particles passed straight through - The atom is mostly empty space.
- A small number were deflected through large angles - The atom's mass and positive charge are concentrated in a tiny central nucleus.
- A few bounced almost straight back - The nucleus is very dense and positively charged, repelling the positive alpha particles.
This led to the nuclear model: a tiny, dense, positively charged nucleus at the centre, surrounded by electrons.

Bohr's energy levels
- Rutherford's model had electrons in a "cloud" around the nucleus, but electrons in this arrangement would spiral inwards, causing the atom to collapse.
- Niels Bohr adapted the model:
- Electrons orbit the nucleus only at fixed distances, called energy levels or shells.
- Electrons can exist in these allowed shells, but not in between them.
- Bohr's theoretical calculations matched experimental observations.

TermDefinition
ElectronA tiny, negatively charged particle found in atoms.
Plum pudding modelAn early model of the atom as a ball of positive charge with negative electrons embedded in it.
Nuclear modelA model of the atom with a tiny, dense, positively charged nucleus at the centre, surrounded by electrons.
Energy levelA fixed distance from the nucleus where electrons can orbit. It is also called a shell.
Key points to remember
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